Quick search
Go!

LA DIMERISATION DE L’ETHYLENE EN PRESENCE DES COMPLEXES MII (2,2’-BIPYRIDINE) (MII = Fe, Co) SUPPORTES SUR ZEOLITHE Y


ZÄ‚VOIANU RODICA 1, BĂŽRJEGA RUXANDRA 2, PAVEL OCTAVIAN DUMITRU 1, CRUCEANU ANCA 1, ANGELESCU EMILIAN 1
(1)UNIVERSITÉ DE BUCAREST, FACULTÉ DE CHIMIE, DÉPARTEMENT DE CHIMIE TECHNOLOGIQUE ET CATALYSE; BD REGINA ELISABETA, NO. 4-12, S3, 030018, BUCAREST, ROUMANIE; E-MAIL: RODICAZAVOIANU@GMAIL.COM (2)INSTITUT NATIONAL DE LA PHYSIQUE DE PLASMA LASERS ET RADIATIO

Issue:

SCSCC6, Volume VII, No. 1

Section:

Volume VII - No. 1 (2006)

Abstract:

The work presents the preparation and characterization of Fe and Co complexes with 2,2’bipyridine (2,2’-bpy) ligands supported on Y zeolite as well as their catalytic activity for ethylene dimerisation. The catalysts were characterized by using XRD, FTIR, DR-UV-Vis spectroscopy and TG-DTA analysis. It was found that Co(2,2’-bpy)2Cl2 supported on Y zeolite has an exceptional good selectivity (>95%) to the formation of 1-butene.

Keywords:

iron complexes, cobalt complexes, 2, 2’-bipyridine, ethylene dimerisation.

Code [ID]:

CSCC6200607V01S01A0018 [0001077]

Full paper:

Download pdf


Copyright (c) 1995-2007 University of Bacău