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DIELS-ALDER AND RETRO-DIELS-ALDER REACTIONS SUPPORTED ON GRAPHITE UNDER MICROWAVES


S. DAHMANI 1, Y. KANDRI RODI 1, K. MISBAHI 1, E. M. ESSASSI 2, BERNARD GARRIGUES 3*
(1) UNIVERSITÉ SIDI MOHAMED BEN ABDALLAH, FACULTÉ DES SCIENCES ET TECHNIQUES, LABORATOIRE DE CHIMIE ORGANIQUE APPLIQUÉE, FES, MAROC
(2) UNIVERSITÉ MOHAMMED V - AGDAL, FACULTÉ DES SCIENCES, LABORATOIRE DE CHIMIE ORGANIQUE HÉTÉROCYCLIQUE, AVENUE IBN-

Issue:

SCSCC6, Volume X, No. 2

Section:

Volume X, No. 2 (2009)

Abstract:

The coupling of graphite (as a support) with microwaves (as an energy source), a new type of « dry reaction », was studied for some Diels-Alder and Hetero-Diels-Alder reactions. It was also possible to achieve in a few minutes, at atmospheric pressure and without solvent, retro-Diels-Alder reactions. All these synthesis have been realized in very short times, without any thermal decomposition products and even in presence of volatile reagents.

Keywords:

microwaves, graphite, Diels-Alder.

Code [ID]:

CSCC6200910V02S01A0004 [0002632]

Full paper:

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