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SYNTHESIS, CRYSTAL STRUCTURE OF A NOVEL 1D CHAINED Na(I) COORDINATION POLYMER MATERIALS BASED ON SCHIFF-BASE LIGAND


LI-HUA WANG
College of Information and Engineering, Weifang University, Weifang 261061, P. R. China
*Corresponding author: wanglihua929@163.com

Issue:

SCSCC6, Volume XV, No. 4

Section:

Volume XV, No. 4 (2014)

Abstract:

A novel 1D chained Na(I) coordination polymer materials has been obtained by reaction of 2-hydrazinobenzoic acid with 2-formyl-benzenesulfonic acid sodium salt in CH3CH2OH/H2O. It was characterized X-ray single crystal diffraction analysis. The crystal of the Na(I) coordination polymer belongs to triclinic, space group P-1 with a = 6.0354(12) Å, b = 8.1922(16) Å, c = 18.729(4) Å, α = 93.70(3)º, β = 95.68(3)º, γ = 97.03(3)º, V = 911.8(3) Å3, Z = 2, Dc = 1.444 μg·m-3, μ= 0.245 mm-1, F(000)= 412, and final R1 = 0.0833, ωR2 = 0.2867. X-ray analysis reveals that each Na(I) center is six-coordination with a O6 distorted octahedron coordination environment. The Na(I) ions are linked through the O atoms of sodium 2-{(E)-[2-(2-carboxyphenyl) hydrazinylidene]methyl}benzenesulfonate to form 1D chain coordination polymer.

Keywords:

sodium 2-{(E)-[2-(2-carboxyphenyl)hydrazinylidene] methyl}benzenesulfonate, Na(I) coordination polymer, structural characterization, synthesis.

Code [ID]:

CSCC6201404V04S01A0004 [0004173]

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