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SYNTHESIS AND CRYSTAL STRUCTURE OF A NA(I) COMPLEX WITH 4,4’-BIPYRIDINE AND 2-FORMYL- BENZENESULFONATE-HYDRAZINE


TAI XI-SHI 1*, WANG GUANG-LI 2, LIU YUAN-YUAN 1
1. College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, P. R. China
2. Weifang Bureau of Quality and Technical Supervision, Weifang 261061, P. R. China
*Corresponding author: taixishi@lzu.edu.cn or taixs@wfu.edu.cn

Issue:

SCSCC6, Volume XVI, No. 2

Section:

Volume XVI, No. 2 (2015)

Abstract:

A Na(I) complex, [Na(4,4’-bipyridine)2·(H2O)4]·L·OH·2H2O (L = 2-formyl-benzenesulfonate-hydrazine), has been synthesized. And its structure was determined by X-ray single crystal diffraction analysis. The Na(I) complex belongs to orthorhombic, space group C2221 with a = 7.9162(16) Å, b = 18.451(4) Å, c = 26.397(5) Å, V= 3855.7(13) Å3, Z = 4, Dc = 1.394 mg·m-3, μ = 0.218 mm-1, F(000) =1689, and final R1 = 0.0683, ωR2 = 0.2017. The result shows that the Na(I) center is six-coordination with a N2O4 distorted octahedral coordination environment. The Na(I) complex forms 1D chain structure by the π-π stacking interaction.

Keywords:

4, 4’-bipyridine, 2-formyl-benzenesulfonate-hydrazine, Na(I) complex, synthesis, structural characterization.

Code [ID]:

CSCC6201502V02S01A0008 [0004237]

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