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Me4NO2CSO3H.2SnPh3Cl AND enH2O2CSO3.SnPh3Cl SYNTHESIS AND INFRARED STUDY


DAOUDA NDOYE 1, LIBASSE DIOP 1*
1. Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, Sénégal
*Corresponding author: dlibasse@gmail.com

Issue:

SCSCC6, Volume XIII, No. 3

Section:

Volume XIII, No. 3 (2012)

Abstract:

Me4NO2C-SO3H.2SnPh3Cl and enH2O2C-SO3.SnPh3Cl are obtained on allowing Me4NO2C-SO3H and enH2O2C-SO3 to react with SnPh3Cl in respectively mixed solution (ethanol/water) or ethanolic solution in specific ratios. Their infrared studies have been carried out and structures as dimers, suggested when hydrogen bonds are involved.

Keywords:

SnPh3 residue, planar geometry, monodentate, bidentate, O2C-SO32- anion, trigonal bipyramidal environment.

Code [ID]:

CSCC6201203V03S01A0010 [0003873]

Full paper:

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