Issue:

SCSCC6, Volume XIV, No. 1

Section:

Volume XIV, No. 1 (2013)

Abstract:

The title adducts have been obtained on allowing Me4NPh2PO2 to react in specific ratios with SnX4 (X = Cl, Br). The infrared data allow to suggest an infinite chain structure, the anion behaving as a bridging ligand, the environment around tin IV being octahedral. In Me4NPhPO3H.SnX4 (X = Cl, Br) when the anion is involved through OH.....O or/and OH.....X hydrogen bonds a supramolecular architecture is obtained.

Keywords:

phenylphosphonate, hydrogenophenylphosphonate, bridging oxyanion, octahedral environment, supramolecular architecture.

Code [ID]:

CSCC6201301V01S01A0006 [0003910]

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