Issue:

SCSCC6, Volume XV, No. 4

Section:

Volume XV, No. 4 (2014)

Abstract:

The proposed structures for the studied adducts - DABCO.3[NiCl2·2H2O].EtOH and 2DABCO.3CuCl2.4EtOH or 3DABCO. 4CuCl2.5EtOH are discrete with two or three metallic components, the environments around the Nickel centres being octahedral or square planar, while being octahedral , linear or a square based prism around the Copper centres, the DABCO behaving as a monodentate or bridging bidentate ligand or being lattice. Extra intermolecular interactions via hydrogen bonds when considered, may lead to supramolecular architectures.

Keywords:

monodentate, bidentate or lattice DABCO, polynuclear adducts with DABCO, octahedral, square planar or linear environments, supramolecular architectures.

Code [ID]:

CSCC6201404V04S01A0006 [0004175]

Full paper:

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