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CETONIZATION, DESARYLATION AND ESTERIFICATION IN THE INTERACTIONS BETWEEN PhPO3H2 AND SnPh3Cl: SYNTHESIS OF OC[OPOSnPh3OEt]2 AND INFRARED STUDY


MODOU SARR, AMINATA DIASSE-SARR, LIBASSE DIOP *
Université Cheikh Anta Diop Faculté des Sciences et Techniques Département de chimie, Laboratoire de Chimie Minérale et Analytique, Dakar- SENEGAL
*Corresponding author: dlibasse@gmail.com

Issue:

SCSCC6, Volume XVI, No. 2

Section:

Volume XVI, No. 2 (2015)

Abstract:

On allowing PhPO3H2 to react with SnPh3Cl in ethanolic media, OC[OPOSnPh3OEt]2 is obtained by cetonization, desarylation and esterification, has been studied by infrared technic. A discrete structure has been suggested on the basis of infrared data, the anion behaving as a bidentate ligand, the environment around the tin centres being tertrahedral.

Keywords:

bidentate, cetonization, desarylation and infrared, hydrogen bonds, phosphonate, SnPh3 residue, supramolecular architectures, tetrahedral environment.

Code [ID]:

CSCC6201502V02S01A0010 [0004239]

Full paper:

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