Issue:

SCSCC6, Volume X, No. 3

Section:

Volume X, No. 3 (2009)

Abstract:

The reaction of trimethyltin (IV) chloride with tetrabutylammonium hydrogenosulphate leads to the formation of Bu₄NHSO₄.SnMe₃Cl, the crystal structure of which has been determined by X-ray analysis. The structure consists of a discrete dimer, in which two hydrogen sulphate anions, each coordinated to a trimethyltin chloride moiety (SnMe₃Cl) are held together by hydrogen bonds. The tin centre displays a trans OClC₃ trigonal bipyramid configuration. Additional infrared, Mössbauer and NMR spectroscopic data are reported.

Keywords:

hydrogenosulphate anion, hydrogen bonded, dimer, infrared, Mössbauer, NMR, X ray diffraction.

Code [ID]:

CSCC6200910V03S01A0001 [0002640]

DOI:

Full paper:

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