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NH3CH2CH2NH3PhCO2SnPhCl3OH, AN UNEXPECTED ADDUCT: SYNTHESIS AND SPECTROSCOPIC STUDIES


KOCHIKPA Y. A. OKIO, LIBASSE DIOP
LABORATOIRE DE CHIMIE MINÉRALE ET ANALYTIQUE (LACHIMIA), DÉPARTEMENT DE CHIMIE, FACULTÉ DES SCIENCES ET TECHNIQUES, UNIVERSITÉ CHEIKH ANTA DIOP DAKAR, SÉNÉGAL *CORRESPONDING AUTHOR: DLIBASSE@GMAIL.COM

Issue:

SCSCC6, Volume XI, No. 2

Section:

Volume XI, No. 2 (2010)

Abstract:

On allowing NH3CH2CH2NH3(PhCO2)2 in slightly hydrated methanol to react with SnPh2Cl2, NH3CH2CH2NH3PhCO2SnPhCl3OH is obtained as a white precipitate. The IR and Mössbauer studies allow to suggest a moiety obtained by addition of OH- and PhCO2- to SnPhCl3, the environment around the tin being octahedral, PhCO2- behaving as a monocoordinating ligand.

Keywords:

phenyl tin compound, benzoate, infrared spectrum, Mössbauer spectrum, polymeric structure.

Code [ID]:

CSCC6201011V02S01A0005 [0002980]

Full paper:

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