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NEW MX2 OXALATO POLYNUCLEAR ADDUCTS (M = Cd, Hg, Zn; X = Cl, Br): SYNTHESIS AND INFRARED STUDY


HAYAT QAMAR-KANE, ALIOUNE FALL, LIBASSE DIOP *
Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Laboratoire de Chimie Minérale et Analytique (LACHIMIA),Dakar, Sénégal
*Corresponding author: dlibasse@gmail.com

Issue:

SCSCC6, Volume XII, No. 4

Section:

Volume XII, No. 4(2011)

Abstract:

Nine mono-, di- and trinuclear MX2 oxalato adducts have been synthesized, their infrared study carried out. The suggested structures are ionic, the oxalate anion behaving as a chelating ligand. Cage structures, when non symmetrical cations are involved,have been suggested.

Keywords:

cage, ionic structures, polychelating oxalate.

Code [ID]:

CSCC6201104V04S01A0006 [0003430]

Full paper:

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