SYNTHESIS AND INFRARED STUDY OF SOME HYDROGENOMOLYBDATO AND MOLYBDATO ADDUCTS OF SbF3, HgPh2 AND MX2
(M = Cd, Hg; X = Cl, Br)
SERIGNE FALLOU POUYE 1, IBRAHIMA CISSE 1*, LIBASSE DIOP 1 ANDDJIBRIL FALL 2, MOUNIROU CISS 2 1. Université Cheikh Anta Diop, Faculté Des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, Sénégal
2. Université Cheikh Anta Diop, Faculté de Médecine, de Pharmacie et d’Odontostomatologie, Département de Pharmacie, Laboratoire de Chimie Organique et Thérapeutique, Dakar, Sénégal
Corresponding author: icisse50@yahoo.fr
Seven molybdato and hydrogenomolybdato new adducts with HgPh2, HgCl2, HgBr2, CdCl2, CdBr2 and SbF3 have been synthesized and characterized by infrared spectroscopy. The suggested structures are discrete, the oxyanions behaving as polychelating ligands. When non symmetrical cations are involved, supramolecular architectures are obtained.
