Quick search
Go!

(Me4N)(NO2)2C6H3CO2 NEW MCl2 (M = Zn, Co, Cd) AND SnR3Cl (R = Me, Ph) ADDUCTS: SYNTHESIS AND INFRARED STUDY


BOCAR TRAORE 1, LIBASSE DIOP 1*, MAMADOU SIDIBE 1
1Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, Sénégal
*Corresponding author: dlibasse@gmail.com

Issue:

SCSCC6, Volume XIV, No. 2

Section:

Volume XIV, No. 2 (2013)

Abstract:

Five new (Me4N)(NO2)2C6H3CO2 adducts with MCl2 (M = Zn, Co, Cd) and SnR3Cl (R = Me, Ph) have been synthesized and studied by infrared spectroscopy. The suggested structures are discrete, the anion behaving as mono- and bichelating ligand towards MX2, tri- and monodentate towards SnR3Cl (R = Me, Ph).The environment around Zn, Co and Cd is tetrahechal, while the tin (IV) centre is trigonal bipyramidal.

Keywords:

[NO2C6H3CO2 ]- ligand, infrared, discrete, structures.

Code [ID]:

CSCC6201302V02S01A0007 [0003918]

Full paper:

Download pdf


Copyright (c) 1995-2007 University of Bacău