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SYNTHESIS AND INFRARED STUDY OF 3(Me4N)2MoO4.2SnBr4 AND (Me4N)2MoO4.SnBr4.H2O

ALEXIS BIENVENU BELEKE, LIBASSE DIOP *
Université Cheikh Anta Diop, Faculté des Sciences et Techniques Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, Sénégal
*Corresponding author: dlibasse@gmail.com

Issue:

SCSCC6, Volume XIV, No. 3

Section:

Volume XIV, No. 3 (2013)

Abstract:

On allowing (Me4N)2MoO4 to react with SnBr4 in specific ratios 3(Me4N)2MoO4.2SnBr4 and (Me4N)2MoO4.SnBr4.H2O adducts were obtained. Their infrared studies have been carried out allowing to suggest a discrete and an infinite chain structures.

Keywords:

coordinating sulphate, dimeric structures, NH…O hydrogen bonds, planar SnMe3 residue, tin (IV) polynuclear complex-anion.

Code [ID]:

CSCC6201303V03S01A0007 [0004027]

DOI:

Full paper:

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