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Cy2NH2NO3SnBu2Cl2•H2O AND Cy2NH2NO3SnPh2Cl2•2H2O: SYNTHESIS AND INFRARED STUDY


ABDOU MBAYE, CHEIKH ABDOUL KHADIR DIOP *, LIBASSE DIOP
Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique Dakar, Sénégal
*Corresponding author: cakdiop@ucad.sn

Issue:

SCSCC6, Volume XV, No. 3

Section:

Volume XV, No. 3 (2014)

Abstract:

On allowing Cy2NH2NO3 to react with SnBu2Cl2 and SnPh2Cl2, the two studied adducts were obtained. While considering the complex-anions [SnBu2Cl2NO3.H2O]- and [NO3.SnPh2Cl2 H2O]-, discrete structures were suggested with monocoordinating nitrate and octahedral environment around the tin centre. When the cation is involved through N-H----O or N-H----Cl hydrogen bonds, suppramolecular architectures are obtained.

Keywords:

discrete structures, monocoordinating O3-, SnR2 residue, suppramolecular architectures.

Code [ID]:

CSCC6201403V03S01A0010 [0004159]

Full paper:

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