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SOME NEW SULFONATO ADDUCT: SYNTHESIS AND SPECTROSCOPIC STUDIES


MOUHAMADOU BIRAME DIOP, LIBASSE DIOP *
Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal
*Corresponding author: dlibasse@gmail.com

Issue:

SCSCC6, Volume XV, No. 4

Section:

Volume XV, No. 4 (2014)

Abstract:

Three new adducts have been synthesized and studied by infrared and NMR spectroscopies. The suggested structures are discrete with a pyridine -3- sulfonate acting as a tri O-chelating and N-donor or as a non σ coordinating ligand, a 4-aminobenzenesulfonate behaving as a monodentate O-donor, the environments around the tin centre being tetrahedral, octahedral or seven coordinated. In all the studied compounds, supramolecular architectures are obtained when hydrogen bonds are considered.

Keywords:

discrete structures, hydrogen bonds, monodentate 4-aminobenzenesulfonate, octahedral, seven coordinated environments, supramolecular architectures, tetrahedral, tri O-chelating and N-donor pyridine -3 - sulfonate.

Code [ID]:

CSCC6201404V04S01A0008 [0004177]

Full paper:

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