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O2CC6H4C6H4CO2(SnPh3)2∙4H2O AND HO2CC6H4C6H4CO2SnBu2Cl: SYNTHESIS AND INFRARED STUDY


ABDOU MBAYE, CHEIKH ABDOUL KHADIR DIOP *, LIBASSE DIOP
Université Cheikh AntaDiop Faculté des Sciences et Techniques Département de Chimie Laboratoire de Chimie Minérale et Analytique Dakar Sénégal
*Corresponding author: cakdiop@ucad.sn

Issue:

SCSCC6, Volume XV, No. 4

Section:

Volume XV, No. 4 (2014)

Abstract:

When the diphenic acid HO2CC6H4C6H4CO2H is allowed to react with SnBu2Cl2 or SnPh3OH, HO2CC6H4C6H4CO2. SnBu2Cl (A) and O2CC6H4C6H4CO2(SnPh3)2∙4H2O(B) were obtained and characterized by infrared spectroscopy. The structures are an infinite chain or an oligomer, the diphenic anion being a monodentate or a monochelating ligand. The environment around the tin centers is trigonal bipyramidal or octahedral.

Keywords:

infinite chain, infrared spectroscopy, monochelating ligand, monodentate, octahedral, oligomer, trigonal bipyramidal.

Code [ID]:

CSCC6201404V04S01A0010 [0004179]

Full paper:

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