MOLYBDATO ORGANOTIN (IV) ADDUCTS AND COMPLEXES: SYNTHESIS AND INFRARED STUDY
MOUHAMADOU BIRAME DIOP *, LIBASSE DIOP Université Cheikh Anta Diop, Faculté des Sciences et Techniques,
Département de Chimie, Laboratoire de Chimie Minérale et Analytique,
Dakar, Sénégal
*Corresponding author: mouhamadoubdiop@gmail.com
Nine new molybdato adducts and complexes have been synthesized and studied by infrared spectroscopy. The suggested structures are discrete or infinite chain, the molybdate behaving as a bidentate, mono-, bi- or tetrachelating ligand, the environment around the tin (IV) centre being octahedral or trigonal bipyramidal. In water containing compounds, when extra intermolecular O-H…O or O-H…Cl hydrogen bonds are considered, supramolecular architectures may be obtained.