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MOLYBDATO ORGANOTIN (IV) ADDUCTS AND COMPLEXES: SYNTHESIS AND INFRARED STUDY


MOUHAMADOU BIRAME DIOP *, LIBASSE DIOP
Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal
*Corresponding author: mouhamadoubdiop@gmail.com

Issue:

SCSCC6, Volume XVI, No. 4

Section:

Volume 16, No. 4 (2015)

Abstract:

Nine new molybdato adducts and complexes have been synthesized and studied by infrared spectroscopy. The suggested structures are discrete or infinite chain, the molybdate behaving as a bidentate, mono-, bi- or tetrachelating ligand, the environment around the tin (IV) centre being octahedral or trigonal bipyramidal. In water containing compounds, when extra intermolecular O-H…O or O-H…Cl hydrogen bonds are considered, supramolecular architectures may be obtained.

Keywords:

bichelating, bidentate, monochelating and monodentate or tetrachelating molybdate, discrete or infinite chain structures, octahedral environment, supramolecular architectures.

Code [ID]:

CSCC6201504V04S01A0007 [0004344]

DOI:

Full paper:

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