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NEW MX2 AND M’Cl3 (M = Cu, Zn; M’= Y, Dy, Pr; X = Cl, Br) MALEATO COMPLEXES AND TETRAPHENYLANTIMONY FORMIATE ADDUCT: SYNTHESIS AND INFRARED STUDY


DAME SEYE *1, CHEIKH ABDOUL KHADIR DIOP 1, ASSANE TOURE 1, LIBASSE DIOP 1
1. Universite Cheikh Anta Diop, Faculte des Sciences et Techniques, Departement de Chimie, Laboratoire de Chimie Minerale et Analytique, Dakar, Senegal
* Corresponding author, email: maviemama2010@yahoo.fr

Issue:

JESR, Number 1, Volume XXIV

Section:

Issue Nr. 1 - Volume 24(2018)

Abstract:

Eleven complexes and adduct have been synthesized and studied by infrared. The suggested structures are discrete with tetrahedral, trigonal bipyramidal, square planar or octahedral environments around Zn, Ni, Hg and Cu centres – the coordination number is eight in the yttrium compound and ten in the dysprosium one-. The maleate anion behaves as a bidentate, a monochelating, a bichelating or a tetradentate ligand while the formiate anion behaves as a monodentate ligand. For compounds containing a protonated amine or a methanol molecule, when hydrogen bonds are considered a supramolecular architecture may be obtained.

Keywords:

bidentate, bichelating, discrete structure, supramolecular architecture.

Code [ID]:

JESR201801V24S01A0005 [0004766]

Note:

DOI:

Full paper:

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