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CARBOXYLATO ADDUCTS AND DERIVATIVES CONTAINING SnR3 (R = Ph, Me) AND SnMe2 RESIDUES: SYNTHESIS, INFRARED AND MĂ–SSBAUER STUDIES

SEYDOU BASSENE 1, MOUHAMADOU SEMBENE BOYE *2, MAMADOU SIDIBE 1, LIBASSE DIOP 1
1. Département de Chimie, Faculté des Sciences et Techniques, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Université Cheikh Anta DIOP, Dakar, Sénégal.
2. Département de Physique Chimie, Faculté des Sciences et Technologies de l’Education et de la Formation, Université Cheikh Anta Diop, Boulevard Habib Bourguiba BP 5036 Fann-Dakar, Sénégal.
*Corresponding author, email: mouhasboye@hotmail.com

Issue:

JESR, Number 3, Volume XXV

Section:

Issue Nr. 3 - Volume 25(2019)

Abstract:

Twelve new carboxylato adducts and derivatives containing SnR3 (R = Ph, Me) and SnMe2 residues have been synthesized and characterized by elemental analyses, infrared and 119Sn-Mossbauer spectroscopies. The proposed structures are discrete or of infinite chain type, the carboxylate anion behaving as a bridging bidentate, a monodentate, a tetradentate or a monochelating ligand.

Keywords:

carboxylate, discrete or infinite chain structures, SnR3 (Ph, Me) and SnMe2 residues, trigonal bipyramidal environment around tin (IV), supramolecular architectures.

Code [ID]:

JESR201903V25S01A0001 [0004945]

Note:

Full paper:

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