SYNTHESIS AND CRYSTAL STRUCTURE OF BIS(ACETATO)BIS(2-METHYL-BENZIMIDAZOLE)COPPER(II)

  • LAMKADDEM A.
    LABORATOIRE DE SYNTHÈSE ORGANIQUE ET DES PROCÉDÉS D’EXTRACTION, UNIVERSITÉ IBN TOFAIL KÉNITRA, MOROCCO
  • ESSASSI E. M.
    LABORATOIRE DE CHIMIE ORGANIQUE HÉTÉROCYCLIQUE, UNIVERSITÉ MOHAMMED V RABAT, MOROCCO
  • LAZAR S.
    LABORATOIRE DE BIOCHIMIE, ENVIRONNEMENT & AGROALIMENTAIRE, UNIVERSITÉ HASSAN II-MOHAMMÉDIA, BP 146, 20800, MOHAMMÉDIA, MOROCCO
  • LÉGER J. M.
  • C. JARRY
  • GUILLAUMET G.

Abstract

The crystal structure of bis(acetato)bis(2-methylbenzimidazole)copper(II) has been determined. The complex is monoclinic, P21/n, with a = 8.128(1) Å, b = 18.577(2) Å, c = 9.524(2) Å and β = 94.92(2)°. The metal is six-coordinated forming with the ligands a slightly distorted octahedron. Eight water molecules were found in the crystal lattice.

Cuvinte cheie

one-dimensional copper coordination complex 2-methylbenzimidazole hydrated copper acetate hydrothermal reaction