SYNTHESIS AND INFRARED STUDY OF SOME NEW MOLYBDATO AND HYDROGENOMOLYBDATO ADDUCTS, DERIVATIVES AND COMPLEXES OF CADMIUM AND ANTIMONY (V)

SERIGNE FALLOU POUYE, IBRAHIMA CISSÉ*, LIBASSE DIOP

UNIVERSITÉ CHEIKH ANTA DIOP, FACULTÉ DES SCIENCES ET TECHNIQUES, DÉPARTEMENT DE CHIMIE, LABORATOIRE DE CHIMIE MINÉRALE ET ANALYTIQUE (LACHIMIA), DAKAR, SÉNÉGAL *CORRESPONDING AUTHOR: ICISSE50@YAHOO.FR

Abstract

Five new molybdato adducts, derivative and complexes of Cd and Sb have been synthesized and studied by infrared. The structures are discrete, the anion behaving as a trichelating and polydentate ligand. The key role of Cy2NH2+ in the supramolecular architecture is noteworthy.

Keywords

coordinating molybdate IR spectra discrete structure supramolecular architecture