ASPECTS CONCERNING THE FORMING INHIBITING OF THE DEPOSITS IN GASOLINES

  • NICULAE ANA DANIELA
    IPIP Ploiesti
  • PETRESCU MARIUS GABRIEL
    Petroleum-Gas University of Ploiesti
  • GEORGESCU OVIDIU
    SC GEXACOR SA Ploiesti
  • GEORGESCU LUCIAN
    George Bariţiu University of Brasov
  • BUCUROIU RODICA
    Petroleum-Gas University of Ploiesti

Abstract

This paper presents results of research on the process of forming gums in gasoline resulted from the pyrolysis of the ethane composition: propane, in a proportion of 1 : 3 in weight, at a temperature of 8200C. In addition, it has been researched the thermal stability of these inhibitors by the thermo-gravimetric analysis (TGA). From the TGA thermo-grams, there were appreciated the temperatures of the losses in weight during the heating process. It was found that the presence of inhibitors does not prevent from the formation of the peroxide radicals, but it prevents from their initiation of the reaction chains. The phenols efficiency is improved by alkylation in the positions 2, 4 and 6. The good results are obtained for the substitutes in all the three positions with a methyl group in para and at least a group of t-butyl in position orto comparing with the hydroxyl

Cuvinte cheie

gasoline pyrolysis inhibitors