NEW R2NH2OH (R = Cy, Bu) ADDUCTS OF MX2, MX3 OR MX5: SYNTHESIS AND INFRARED STUDY

  • NDONGO GUEYE
    Université Cheikh Anta Diop, Faculté des Sciences et Technique, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal
  • LIBASSE DIOP
    Université Cheikh Anta Diop, Faculté des Sciences et Technique, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal
    dlibasse@gmail.com
  • LAMINE DIOP
    Collège Universitaire de Saint-Boniface, Winnipeg, Canada

Abstract

When Cy2NH and Bu2NH in the presence of a very little amount of water are allowed to react with metal halide CdBr2, SbCl3 or SbCl5, hydroxyl adducts with protonated amines as adverse cations were obtained. Their infrared study allows concluding the presence of OH- linked to the metallic center.

Cuvinte cheie

discrete structure octahedral environment Sb adducts