2[(enH)2O2C-SO3].SnPhCl3 AND Cy2NH2O2C-SO3H.SnPhCl3.H2O: SYNTHESIS AND INFRARED STUDY
DAOUDA NDOYE, LIBASSE DIOP*
Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, Sénégal
*Corresponding author: dlibasse@gmail.com
Abstract
By allowing (enH)2O2C-SO3 (in water) and Cy2NH2O2C-SO3 (in ethanol) to react respectively with SnPh3Cl (in water) and SnPh2Cl2 (in ethanol) in specific ratios, the studied complexes are obtained. The suggested structures are discrete and tetrameric, the environment of the tin center being octahedral, the O2C-SO3H- anions behaving as a monodentate or a monochelating ligand.