Cy2NH2NO3SnBu2Cl2•H2O AND Cy2NH2NO3SnPh2Cl2•2H2O: SYNTHESIS AND INFRARED STUDY
ABDOU MBAYE, CHEIKH ABDOUL KHADIR DIOP(*), LIBASSE DIOP
Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique Dakar, Sénégal *Corresponding author: cakdiop@ucad.sn
Abstract
On allowing Cy2NH2NO3 to react with SnBu2Cl2 and SnPh2Cl2, the two studied adducts were obtained. While considering the complex-anions [SnBu2Cl2NO3.H2O]- and [NO3.SnPh2Cl2 H2O]-, discrete structures were suggested with monocoordinating nitrate and octahedral environment around the tin centre. When the cation is involved through N-H----O or N-H----Cl hydrogen bonds, suppramolecular architectures are obtained.