UNDERSTANDING OF OXYGEN TRANSPORT MECHANISMS THROUGH DENSE PEROVSKITE CERAMIC MEMBRANES

  • GUIRONNET LAURE
    Laboratoire SPCTS-CNRS UMR7315, 12 rue Atlantis, 87068 Limoges, France ,ADEME, BP90406 – 20 rue du Grésillé, 49004 Angers, France
  • GEFFROY PIERRE-MARIE
    Laboratoire SPCTS-CNRS UMR7315, 12 rue Atlantis, 87068 Limoges, France
  • RICHET NICOLAS
    Air Liquide CRCD, BP126, 78354 Jouy Josas, France
  • CHARTIER THIERR
    Laboratoire SPCTS-CNRS UMR7315, 12 rue Atlantis, 87068 Limoges, France

Abstract

For last decades, important research activities have led to the improvement of electrochemical devices for energy production. Our last researches lead us to the development of a specific experimental setup which allows the determination of the oxygen activity of the membrane surfaces and in gas. These measurements of oxygen activities at the membranes surfaces give us essential data for the better understanding of the membrane surface oxygen exchange mechanisms corresponding to the determining rate step of oxygen transport through the dense ceramic membranes.

Cuvinte cheie

ceramic membrane perovskite mixed conductor oxygen semi-permeation surface exchange mechanism bulk diffusion coating synthesis.