NITRATO ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY

  • MOUHAMADOU BIRAME DIOP
    Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal
    mouhamadoubdiop@gmail.com
  • LIBASSE DIOP
    Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal

Abstract

Five new nitrato adducts and derivatives have been synthesized and studied by infrared spectroscopy. The suggested structures are discrete or of infinite chain type, the nitrate behaving as a bidentate or a monodentate ligand, the environment around the tin (IV) centres being octahedral or trigonal bipyramidal. When extra hydrogen bonds are considered supramolecular architectures may be obtained.

Cuvinte cheie

bidentate monodentate nitrate discrete and infinite chain structures octahedral or trigonal bipyramidal environments supramolecular architectures