INTERMOLECULAR RESONANCE ENERGY TRANSFER IN THE PRESENCE OF METALLIC NANOPARTICLES: FINITE ELEMENT SIMULATIONS

  • TITUS SANDU
    National Institute for Research and Development in Microtechnologies-IMT, 126A, Erou Iancu Nicolae Street, Bucharest, Romania
  • CATALIN TIBEICA
    National Institute for Research and Development in Microtechnologies-IMT, 126A, Erou Iancu Nicolae Street, Bucharest, Romania
  • OANA NEDELCU
    National Institute for Research and Development in Microtechnologies-IMT, 126A, Erou Iancu Nicolae Street, Bucharest, Romania
  • MIHAI GOLOGANU
    National Institute for Research and Development in Microtechnologies-IMT, 126A, Erou Iancu Nicolae Street, Bucharest, Romania

Abstract

Plasmon resonances in metallic nanoparticles augment the Förster resonance
energy transfer (FRET) between two molecules. We calculate and analyze comparatively
the enhancement factors of FRET for a metallic nanosphere and for a metallic spherical
nanoshell by finite element method (FEM). These calculations are compared with analytical
results obtained from the knowledge of spectral properties of the Neumann-Poincaré
(electrostatic) operator for sphere. With respect to the plain metallic nanosphere, the
spherical nanoshell shows a greater tunability of energy range for which the energy transfer
is enhanced. Our work can be relevant for using FRET for various applications regarding
porous materials.

Cuvinte cheie

Plasmonics; boundary integral equation method; Neumann-Poincaré (electrostatic) operator; finite element method; Förster resonance energy transfer.