INTERMOLECULAR RESONANCE ENERGY TRANSFER IN THE PRESENCE OF METALLIC NANOPARTICLES: FINITE ELEMENT SIMULATIONS

TITUS SANDU1*, CATALIN TIBEICA1, OANA NEDELCU 2, MIHAI GOLOGANU 1

1 National Institute for Research and Development in Microtechnologies-IMT, 126A, Erou Iancu Nicolae Street, Bucharest, Romania
*titus.sandu@imt.ro

Abstract

Plasmon resonances in metallic nanoparticles augment the Förster resonance energy transfer (FRET) between two molecules. We calculate and analyze comparatively the enhancement factors of FRET for a metallic nanosphere and for a metallic spherical nanoshell by finite element method (FEM). These calculations are compared with analytical results obtained from the knowledge of spectral properties of the Neumann-Poincaré (electrostatic) operator for sphere. With respect to the plain metallic nanosphere, the spherical nanoshell shows a greater tunability of energy range for which the energy transfer is enhanced. Our work can be relevant for using FRET for various applications regarding porous materials.

Keywords

Plasmonics boundary integral equation method Neumann-Poincaré (electrostatic) operator finite element method Förster resonance energy transfer.