INTERACTIONS BETWEEN CETYLTRIMETHYLAMMONIUM OR TETRAMETYLAMMMONIUM BROMIDE AND MCl2 OR MCl5 (M = Hg, Cu, Zn, Co, Ni, Cd and Nb) IN MONONUCLEAR COMPLEXES: SYNTHESIS AND INFRARED STUDY

Autori: DAME SEYE(*1), ASSANE TOURE(1), CHEIKH ABDOUL KHADIR DIOP(1), LIBASSE DIOP(1)

1. Cheikh Anta Diop University, Faculty of Science and Technology, Department of Chemistry, Laboratory of Mineral and Analytical Chemistry, Dakar, Senegal
*Corresponding author: maviemama2010@yahoo.fr

Abstract

On allowing cetyltrimethyl ammonium bromide (C19H42NBr) and HgCl2, CuCl2.2H2O, CoCl2.6H2O, ZnCl2, NiCl2.6H2O or NbCl5 in specific ratio in methanol, new mononuclear have been obtained and studied by infrared. The suggested structures are discrete, of infinite chain with octahedral or tetrahedral environments around the metallic centres. The MX2 behaves as discrete chains. For most of the structures, when intermolecular hydrogen bonds are considered, supramolecular architectures may be obtained.

Cuvinte cheie

intermolecular hydrogen bonds discrete structures infinite chain supramolecular architecture