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Ph3CCOOSnPh3.Ph3PO AND Ph3CCOOSnPh3.Ph3AsO: SYNTHESIS AND INFRARED STUDY


ABDOU MBAYE, ALEXIS BIENVENU BELEKE, CHEIKH ABDOUL KHADIR DIOP *, LIBASSE DIOP
Université Cheikh Anta Diop Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal
*Corresponding author: cakdiop@ucad.sn

Issue:

SCSCC6, Volume XV, No. 2

Section:

Volume XV, No. 2 (2014)

Abstract:

The mixture of ethanolic solutions of Ph3CCOOSnPh3 and Ph3PO or Ph3AsO gives Ph3CCOOSnPh3.Ph3PO and Ph3CCOOSnPh3.Ph3AsO adducts which have been characterized by infrared spectroscopy. A discrete structure is suggested for both, the environment around the tin centre being trigonal bipyramidal, the triphenylacetate anion behaving as a mondentate ligand

Keywords:

discrete structure, infrared spectroscopy, mondentate ligand, trigonal bipyramidal environment.

Code [ID]:

CSCC6201402V02S01A0010 [0004149]

DOI:

Full paper:

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