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NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N’N’ (CH2CO2)(CH2CO2H)3 ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY


GORGUI AWA SECK 1, ABOUBACRY SENE 1*, LIBASSE DIOP 1
1. Université Cheikh Anta Diop, Faculté des Sciences et Techniques- Département de Chimie, Laboratoire de Chimie Minérale et Analytique, DAKAR, Senegal
* Corresponding author email: abousene2000@yahoo.fr

Issue:

JESR, Number 4, Volume XXIII

Section:

Issue Nr. 4 - Volume 23(2017)

Abstract:

Five Cyclohexyldiamino-NN, N’N’(CH2CO2)(CH2CO2H)3 anion containing adducts and derivatives with tin, antimony and mercury halides have been synthesized and characterized by infrared spectroscopy. The suggested structures are discrete, the anion behaving as a monodentate or a monochelating ligand: the environments around the metallic centres are trigonal bipyramidal or octahedral.The carboxylic groups and the cation, when involved in extra OH---O, OH----Cl or NH---Cl or O hydrogen bonds may lead to supramolecular architectures.

Keywords:

monodentate or monochelating ligand, supramolecular architectures, trigonal bipyramidal or octahedral environments.

Code [ID]:

JESR201704V23S01A0005 [0004760]

Note:

DOI:

Full paper:

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