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ADSORPTIVE REMOVAL OF A CATIONIC DYE - BASIC RED 46 - FROM AQUEOUS SOLUTIONS USING ANIMAL BONE MEAL


EL HADDAD MOHAMMADINE 1, 2, SLIMANI RACHID 2, MAMOUNI RACHID 3, SAFFAJ NABIL 4, RIDAOUI MOHAMED 5, LAZAR SAĂŹD 2
1. Equipe de Chimie Analytique & Environnement, 5Laboratoire de l’Environnement littoral & Marin, Faculté Poly-disciplinaire, Université Cadi Ayyad, BP 4162, 46000 Safi, Maroc
2. Laboratoire de Biochimie, Environnement & Agroalimentaire, Faculté des Sciences & Techniques, Université Hassan II, BP 146, 20800 Mohammedia, Maroc
3. Laboratoire de Chimie Organique, Equipe de Chimie Bio-Organique Appliquée, Faculté des Sciences
4. Faculté Poly-disciplinaire d’Ouarzazate, Université Ibn Zohr, BP 8061, 80000 Agadir, Maroc
5. Laboratoire de l’Environnement littoral & Marin, Faculté Poly-disciplinaire, Université Cadi Ayyad, BP 4162, 46000 Safi, Maroc

Issue:

JESR, Number 3, Volume XVIII

Section:

Issue No. 3 - Volume 18 (2012)

Abstract:

Removal of Basic Red 46 from aqueous media was achieved onto Animal Bone Meal as a new low cost adsorbent. The latter was characterized by Infra-Red and X-ray diffraction. The adsorption of Basic Red 46 was occurred by studying the effects of adsorbent amount, dye concentration, contact time, pH media and temperature. The adsorption rate data were analyzed using the pseudo-first order and the pseudo-second order kinetics models to determine adsorption rate constants. The isotherms of adsorption data were analyzed by both adsorption isotherm models Langmuir and Freundlich. The monolayer adsorption capacity is 76 mg/g of animal bone meal. Nearly 30 minutes of contact time was found to be sufficient for the dye adsorption to reach equilibrium. Thermodynamic parameters were also evaluated for the dye-adsorbent system and revealed that the adsorption process is endothermic in nature. All results found concluded that animal bone meal could be effectively employed as effective new low cost adsorbent for the removal textile dyes from aqueous solutions.

Keywords:

Animal Bone Meal, cationic dye, adsorption, kinetics, equilibrium, thermodynamic studies.

Code [ID]:

JESR201203V18S01A0007 [0003663]

Full paper:

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