CETONIZATION, DESARYLATION AND ESTERIFICATION IN THE INTERACTIONS BETWEEN PhPO3H2 AND SnPh3Cl: SYNTHESIS OF OC[OPOSnPh3OEt]2 AND INFRARED STUDY
MODOU SARR, AMINATA DIASSE-SARR, LIBASSE DIOP * Université Cheikh Anta Diop Faculté des Sciences et Techniques Département de chimie, Laboratoire de Chimie Minérale et Analytique, Dakar- SENEGAL
*Corresponding author: dlibasse@gmail.com
On allowing PhPO3H2 to react with SnPh3Cl in ethanolic media, OC[OPOSnPh3OEt]2 is obtained by cetonization, desarylation and esterification, has been studied by infrared technic. A discrete structure has been suggested on the basis of infrared data, the anion behaving as a bidentate ligand, the environment around the tin centres being tertrahedral.
