Abstract
Two new tetranuclear (sulphato)(halo)triphenyltin(IV) complexes (halo = F, Cl) have been synthesized and studied by infrared and Mossbauer spectroscopies. The suggested structures are discrete, the anion acting as a bichelating, a monochelating and monocoordinating or a bidentate ligand. The key role of the cation, which appears to link the two components of the structures via hydrogen bonds, is noteworthy.
Cuvinte cheie
asulphato
triphenyltin(IV)
fluoro
chloro
hydrogen bonds