DIELS-ALDER AND RETRO-DIELS-ALDER REACTIONS SUPPORTED ON GRAPHITE UNDER MICROWAVES

  • BERNARD GARRIGUES
  • E.M. ESSASSI
    UNIVERSITÉ MOHAMMED V - AGDAL, FACULTÉ DES SCIENCES, LABORATOIRE DE CHIMIE ORGANIQUE HÉTÉROCYCLIQUE
  • K. MISBAHI
    UNIVERSITÉ SIDI MOHAMED BEN ABDALLAH, FACULTÉ DES SCIENCES ET TECHNIQUES, LABORATOIRE DE CHIMIE ORGANIQUE APPLIQUÉE, FES, MAROC
  • S. DAHMANI
    UNIVERSITÉ SIDI MOHAMED BEN ABDALLAH, FACULTÉ DES SCIENCES ET TECHNIQUES, LABORATOIRE DE CHIMIE ORGANIQUE APPLIQUÉE, FES, MAROC
  • Y. KANDRI RODI
    UNIVERSITÉ SIDI MOHAMED BEN ABDALLAH, FACULTÉ DES SCIENCES ET TECHNIQUES, LABORATOIRE DE CHIMIE ORGANIQUE APPLIQUÉE, FES, MAROC

Abstract

The coupling of graphite (as a support) with microwaves (as an energy source), a new type of « dry reaction », was studied for some Diels-Alder and Hetero-Diels-Alder reactions. It was also possible to achieve in a few minutes, at atmospheric pressure and without solvent, retro-Diels-Alder reactions. All these synthesis have been realized in very short times, without any thermal decomposition products and even in presence of volatile reagents.

Cuvinte cheie

microwaves graphite Diels-Alder