NH3CH2CH2NH3PhCO2SnPhCl3OH, AN UNEXPECTED ADDUCT: SYNTHESIS AND SPECTROSCOPIC STUDIES

KOCHIKPA Y.A. OKIO, LIBASSE DIOP

LABORATOIRE DE CHIMIE MINÉRALE ET ANALYTIQUE (LACHIMIA), DÉPARTEMENT DE CHIMIE, FACULTÉ DES SCIENCES ET TECHNIQUES, UNIVERSITÉ CHEIKH ANTA DIOP DAKAR, SÉNÉGAL *CORRESPONDING AUTHOR: DLIBASSE@GMAIL.COM

Abstract

On allowing NH3CH2CH2NH3(PhCO2)2 in slightly hydrated methanol to react with SnPh2Cl2, NH3CH2CH2NH3PhCO2SnPhCl3OH is obtained as a white precipitate. The IR and Mössbauer studies allow to suggest a moiety obtained by addition of OH- and PhCO2- to SnPhCl3, the environment around the tin being octahedral, PhCO2- behaving as a monocoordinating ligand.

Keywords

phenyl tin compound benzoate infrared spectrum Mössbauer spectrum polymeric structure