NEW ORGANOTIN (IV) OXALATO ADDUCTS: SYNTHESIS AND SPECTROSCOPIC STUDIES
SEYDI MANSOUR SY SECK(1), LIBASSE DIOP(1*), LORENZO STIEVANO(2)
1. Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, Sénégal
2. Université Montpellier II, ICGm-AIME, UMR 5253, Montpellier, France
(*)Corresponding author: dlibasse@yahoo.fr
Abstract
Seven new oxalato organotin (IV) adducts have been synthesized, their infrared and Mössbauer studies carried out. Their structures are discrete, the oxalate behaving as a chelating or bridging ligand. The key role of the cation is noteworthy.