WHEAT FLOUR HUMIDITY VARIATION WITH UV-VIS RADIATION DOSE REVEALED BY SPECTRAL AND CHEMOMETRIC STUDIES

  • IULIANA MIHAELA LAZĂR
    "Vasile Alecsandri" University of Bacău, Department of Chemical and Food Engineering, Calea Mărăşeşti 157, 600115 Bacău, Romania
  • ALINA MIHAELA MOROI
    "Vasile Alecsandri" University of Bacău, Department of Chemical and Food Engineering, Calea Mărăşeşti 157, 600115 Bacău, Romania
  • IRINA LOREDANA IFRIM
    "Vasile Alecsandri" University of Bacău, Department of Chemical and Food Engineering, Calea Mărăşeşti 157, 600115 Bacău, Romania
    irinaifrim@ub.ro
  • NICOLETA VARTOLOMEI
    "Vasile Alecsandri" University of Bacău, Department of Chemical and Food Engineering, Calea Mărăşeşti 157, 600115 Bacău, Romania
  • ALISA-VASILICA ARUŞ
    "Vasile Alecsandri" University of Bacău, Department of Chemical and Food Engineering, Calea Mărăşeşti 157, 600115 Bacău, Romania

Abstract

The cells’ exposure to UV radiation induces mutations of the cellular components by its action on DNA, protein synthesis and enzymatic activities. Different varieties of wheat flour were treated with UV-B, UV-A, Vis radiation and compared with untreated samples. The IR spectra for these components were recorded with a Bruker FTIR spectrophotometer using an ATR method, at 4 cm-1 resolution. The paper proposes a comparative study of unmaturing flour behavior under UV-Vis and natural radiations in order to observe the physico-chemical changing by FTIR spectroscopy. At small doses of irradiation (up to 2 h) the humidity of the samples decreases and then it significantly increases, most pronounced in Gruia’s case where the humidity is reaching 74.4% of the initial value. Middle infrared spectral studies reveal an inverse weak linear correlation between Amide I region (1650 cm-1) (R-squared value: -0.3168) and an inverse medium linear correlation assigned to area alcohol O-H band at 3290 cm-1 (R-squared value: -0.6064) with the irradiation dose variables. Strong direct linear correlations confirmed by R-squared value: 0.7835 are found between alcohol O-H band at 3290 cm-1 and humidity percentage parameter.

Cuvinte cheie

FTIR spectroscopy and chemometrics irradiation maturation wheat flour