ANTIMONY HALIDES AND HgX2 (X = Cl, Br) AMINE ADDUCTS: SYNTHESIS AND INFRARED STUDY

  • NDONGO GUEYE
    Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar Senegal
  • LIBASSE DIOP
    Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar Senegal
    dlibasse@gmail.com
  • LAMINE DIOP
    Collège Universitaire de Saint-Boniface, Winnipeg, Canada

Abstract

Eight new SbF3, SbCl5 and HgX2 (X = Cl, Br) amine adducts have been synthesized and their infrared study carried out. Discrete structures have been suggested on the basis of elemental analysis and infrared data, the coordination number of antimony varying from five to nine, while the environment around Hg is tetrahedral.

Cuvinte cheie

SbF3 SbCl5 and HgX2 (X = Cl Br) amine discrete structures