Me4NO2CSO3H.2SnPh3Cl AND enH2O2CSO3.SnPh3Cl SYNTHESIS AND INFRARED STUDY

DAOUDA NDOYE(1), LIBASSE DIOP(1*)

1. Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, Sénégal
*Corresponding author: dlibasse@gmail.com

Abstract

Me4NO2C-SO3H.2SnPh3Cl and enH2O2C-SO3.SnPh3Cl are obtained on allowing Me4NO2C-SO3H and enH2O2C-SO3 to react with SnPh3Cl in respectively mixed solution (ethanol/water) or ethanolic solution in specific ratios. Their infrared studies have been carried out and structures as dimers, suggested when hydrogen bonds are involved.

Keywords

SnPh3 residue planar geometry monodentate bidentate O2C-SO32- anion trigonal bipyramidal environment