NEW HYDROGENOMOLYBDATO SnPh2 AND SnPh3 RESIDUE CONTAINING ADDUCT AND DERIVATIVE: SYNTHESIS AND INFRARED STUDY
SERIGNE FALLOU POUYE(1*), IBRAHIMA CISSE(1), LIBASSE DIOP(1), LAMINE A.DIOP(2)
1. Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LA.CHI.MI.A) 2. Saint Boniface College, Département de Chimie Organique, Saint Boniface, Winnipeg-Canada *Corresponding authors: sgne0281@yahoo.fr
Abstract
Three new organostannic complex, adduct and derivative have been synthesized and studied by infrared. Dimeric structures involving the cations were suggested on the basis of infrared data. The molybdate anion behaves as a non coordinating ligand-only involved in hydrogen bonds-, mono- or bicoordinating and always involved in hydrogen bonds. The environment of the tin centres is trigonal bipyramidal or octahedral.