Abstract
Three new organostannic complex, adduct and derivative have been synthesized and studied by infrared. Dimeric structures involving the cations were suggested on the basis of infrared data. The molybdate anion behaves as a non coordinating ligand-only involved in hydrogen bonds-, mono- or bicoordinating and always involved in hydrogen bonds. The environment of the tin centres is trigonal bipyramidal or octahedral.
Cuvinte cheie
dimeric structures hydrogen bonds
non coordinating
mono- and bicoordinating ligand
trigonal bipyramidal