A NEW AND CONCISE SYNTHESIS OF 3-HYDROXYLATED 3-ARYLISOINDOLINONES </br> NOUVELLE TECHNIQUE D'ASSEMBLAGE DE 3-ARYLISOINDOLINONES HYDROXYLEES EN POSITION 3

MAGALI LORION(1,2), AXEL COUTURE(1,3), PIERRE GRANDCLAUDON(1,2*)

1. Université Lille Nord de France, F-59000 Lille, France
2. USTL, Laboratoire de Chimie Organique Physique, EA CMF 4478, Bâtiment C3(2), F-59655 Villeneuve d'Ascq, France
3. CNRS, UMR 8181 'UCCS', F-59655 Villeneuve d'Ascq, France
*Corresponding author: pierre.grandclaudon@univ-lille1.fr

Abstract

A new technique for the assembly of diversely substituted 3-hydroxy(alkoxy)-3-arylisoindolinones has been developed. This new synthetic route is based upon the anionic cyclization of suitably substituted halogenoaroyl acylamines as the key step and gives access to a variety of highly functionalized models.

Keywords

diacylamines metal-halogen conversion anionic cyclization Parham type cyclization isoindolinones