SOME NEW SULFONATO ADDUCT: SYNTHESIS AND SPECTROSCOPIC STUDIES

  • MOUHAMADOU BIRAME DIOP
    Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal
  • LIBASSE DIOP
    Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique, Dakar, Sénégal
    dlibasse@gmail.com

Abstract

Three new adducts have been synthesized and studied by infrared and NMR spectroscopies. The suggested structures are discrete with a pyridine -3- sulfonate acting as a tri O-chelating and N-donor or as a non σ coordinating ligand, a 4-aminobenzenesulfonate behaving as a monodentate O-donor, the environments around the tin centre being tetrahedral, octahedral or seven coordinated. In all the studied compounds, supramolecular architectures are obtained when hydrogen bonds are considered.

Cuvinte cheie

discrete structures hydrogen bonds monodentate 4-aminobenzenesulfonate octahedral seven coordinated environments supramolecular architectures tetrahedral tri O-chelating and N-donor pyridine -3 - sulfonate