NEW HALOTIN (IV) WITH EDTA: SYNTHESIS AND INFRARED STUDY

  • SERIGNE CISSE
    Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, Sénégal
  • IBRAHIMA CISSE
    Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, Sénégal
  • LIBASSE DIOP
    Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, Sénégal
    dlibasse@gmail.com

Abstract

Tri acidic or neutral ethylenediaminetetraacetato [H3Y- or Y4-] containing adducts and derivatives have been synthesized and studied by infrared. The suggested structures are discrete with octahedral environments around the tin centres, the thylenediaminetetraacetic anion behaving as a tridentate, pentachelating and bidentate, pentachelating and tridentate ligand. For the last structure when intermolecular hydrogen bonds involving OH group are considered, a supramolecular architecture may be obtained.

Cuvinte cheie

discrete structures ethylenediaminetetraacetic anion hydrogen bonds pentachelating and bidentate pentachelating and tridentate supramolecular architectures