STUDY REGARDING THE DESTABILIZATION OF STABLE EMULSIONS FROM SUPLAC AREA

  • IULIANA VERONICA GHEŢIU
    etroleum Gas University of Ploiesti, Faculty of Petroleum and Gas Engineering/Drilling, Extraction and Transport of Hydrocarbons Department, 39 Bucuresti Blvd., 100680, Ploiesti, Romania
  • IOANA GABRIELA STAN
    etroleum Gas University of Ploiesti, Faculty of Petroleum and Gas Engineering/Drilling, Extraction and Transport of Hydrocarbons Department, 39 Bucuresti Blvd., 100680, Ploiesti, Romania
  • MARIA GEORGETA POPESCU
    etroleum Gas University of Ploiesti, Faculty of Petroleum and Gas Engineering/Drilling, Extraction and Transport of Hydrocarbons Department, 39 Bucuresti Blvd., 100680, Ploiesti, Romania

Abstract

Emulsions from the wells in the Suplac area create great difficulties in removing water due to their specifications. A complex study was conducted in order to eliminate water from emulsions using alkaline-surfactants. The choice of surfactant was made after the chromatographic SARA analysis of emulsions and the determination of their physical properties: density, viscosity, organic acidity. The samples were taken from two wells in the Suplac area. In the case of samples from A well the variation of density is 907 - 955 kg·m-3 for crude oil and 928 - 970 kg·m-3 for emulsion, while the rheological behavior of the emulsion varies between 0.680 to 0.995 Pa·s at a temperature of 25 °C and between 0.049 to 0.328 Pa·s at a temperature of 80 °C. For samples from B well the variation of density is 855 - 905 kg·m-3 for crude oil and 939 - 970 kg·m-3 for emulsion, while the rheological behavior of the emulsion varies between 0.149 to 0.797 Pa·s at a temperature of 25 °C and between 0.014 to 0.397 Pa·s at a temperature of 80 °C. The justification for choosing R - DP surfactant like reagent was based on laboratory tests which showed a maximum efficiency at 80 °C (95.69 for B and 98.75 % for A).

Cuvinte cheie

aromatic asphaltene emulsion breaking agents resin saturated water/oil emulsion